Na’ama Goldman sprang to fame when she jumped in at the last moment as Carmen at the Masada Opera Festival 2012, under the baton of Maestro Daniel Oren. Her success led to celebrated debuts at The Israeli Opera, such as Charlotte in Werther, the title role in La Cenerentola, Donna Elvira in Don Giovanni, Rosina in Il barbiere di Siviglia, Idamante in Idomeneo, Dorabella in Così fan tutte, Fenena in Nabucco, Cherubino in Le nozze di Figaro, and a return as Carmen in season 2018 / 19.
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On the international stages, she interpreted many roles including Salomé (A. Mariotte) at Wexford Festival Opera, Rosinain Il barbiere di Siviglia at Teatro Lirico di Cagliari, a tournée of Carmen with AsLiCo in Cremona, Brescia, Pavia and Como, as well as performing Carmen at Ópera de Tenerife and at The Grange Festival, Marchesa Melibea in Il viaggio a Reims at Rossini Opera Festival in Pesaro, Fenena in Nabucco and Siébel in Faust at Opéra Royal de Wallonie, Dorabellain Così fan tutte at Ópera de Tenerife, Cornelia in Giulio Cesare at Shanghai Baroque Festival, and more.
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In concert, Na’ama performed the cantata Arianna a Naxos by Haydn at Wiener Konzerthaus, Stabat Mater by Rossini in Teatro Lirico Cagliari, Missa Solemnis by Beethoven and the title role in Solomon by Händel with the Jerusalem Symphony Orchestra, a vocal chamber music concert at Deutsche Oper Berlin, Symphony no. 9 by Beethoven with Taiwan Philharmonic, and many more. 

She also performed numerous recitals and gala concerts in Italy, Spain, Germany, Switzerland, Austria, Russia, Israel, South Korea, China, United Kingdom, and Australia.
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As a graduate of the Meitar Opera Studio of The Israeli Opera, she performed a vast variety of roles such as Charlotte in Werther, the title role in La Cenerentola, Hänsel in Hänsel und Gretel, Prince Orlofsky in Die Fledermaus, Zweite Damein Die Zauberflöte, and many others. 

The recent engagements on Na’ama Goldman include Idamante in Idomeneo, Charlotte in Werther and Dorabella in cosí fan tutte at the Israeli Opera.
Rosina in il Barbiere di Siviglia in Teatro Lirico di Cagliari, Siébel in Faust at Opera de Wallonie, and the title role of Carmen in a tournée with ASLICO in Cremona, Brescia, Pavia, and Como.

Her future engagements include the role of Maffio Orsini, in Lucrezia Borgia at Opera de Tenerife, Carmen at the Israeli Opera, among others.